Process for preparing basestocks having high VI using oxygenated dewaxing catalyst

ABSTRACT

A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.

CROSS-REFERENCE TO RELATED APPLICATION

This patent application claims benefit of U.S. Provisional PatentApplication Ser. No. 60/416,870 filed Oct. 8, 2002.

FIELD OF THE INVENTION

This invention relates to a process for preparing lubricating oilbasestocks having a high viscosity index (VI) from wax containing feeds.More particularly, a wax containing feedstock is hydrotreated under mildconditions, catalytically hydrodewaxed using a dewaxing catalyst whichhas been selectively activated by treatment with an oxygenate, andhydrofinished.

BACKGROUND OF THE INVENTION

Historically, lubricating oil products for use in applications such asautomotive engine oils have used additives to improve specificproperties of the basestocks used to prepare the finished products. Withthe advent of increased environmental concerns, the performancerequirements for the basestocks themselves have increased. AmericanPetroleum Institute (API) requirements for Group II basestocks include asaturates content of at least 90%, a sulfur content of 0.03 wt. % orless and a viscosity index (VI) between 80 and 120. The requirements forGroup III basestocks are those of Group II basestocks except that the VIis at least 120.

Conventional techniques for preparing basestocks such as hydrocrackingor solvent extraction require severe operating conditions such as highpressure and temperature or high solvent:oil ratios and high extractiontemperatures to reach these higher basestock qualities. Eitheralternative involves expensive operating conditions and low yields.

Hydrocracking has been combined with hydrotreating as a preliminarystep. However, this combination also results in decreased yields oflubricating oils due to the conversion to distillates that typicallyaccompany the hydrocracking process.

It would be desirable to have a economical process for preparing GroupIII basestocks in high yields by minimizing conversion to low boilingdistillates while at the same time producing a product having excellentlow temperature properties, high VI and high stability.

SUMMARY OF THE INVENTION

The present invention is directed to a process for preparing alubricating oil basestock having a VI of at least about 125 whichcomprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) contacting a dewaxing catalyst with a stream containing at leastabout 100 wppm, measured as oxygen, of at least one oxygenate at atemperature of from 120 to 400° C. and a hydrogen pressure of from 791to 20786 kPa to produce a selectivated dewaxing catalyst; and

(d) contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions.

Another embodiment relates to a process for preparing a lubricating oilbasestock having a VI of at least about 125 which comprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) contacting a dewaxing catalyst which contains at least one molecularsieve containing at least one 10 or 12 ring channel with a streamcontaining at least about 100 wppm, measured as oxygen, of at least onealcohol, carboxylic acid, ester, aldehyde, ketone or ether at atemperature of from 120 to 400° C. and a hydrogen pressure of from 101to 20786 kPa to produce a selectivated dewaxing catalyst; and

(d) contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions.

Yet another embodiment relates to a process for preparing a lubricatingoil basestock having a VI of at least about 125 which comprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) contacting a dewaxing catalyst which contains at least one molecularsieve containing at least one 10 or 12 ring channel with a streamcontaining at least about 100 wppm, measured as oxygen, of at least onealcohol, carboxylic acid, ester, aldehyde, ketone or ether at atemperature of from 120 to 400° C. and a hydrogen pressure of from 101to 20786 kPa to produce a selectivated dewaxing catalyst;

(d) contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions; and.

(e) hydrofinishing the dewaxed product from step (d) with ahydrofinishing catalyst under effective hydrofinishing conditions.

A still further embodiment relates to a process for preparing alubricating oil basestock having a VI of at least about 125 whichcomprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) contacting a dewaxing catalyst which contains ZSM-48 and a metalhydrogenation component which contains at least one of Pt or Pd with astream containing at least about 100 wppm, measured as oxygen, of atleast one alcohol, carboxylic acid, ester, aldehyde, ketone or ether ata temperature of from 120 to 400° C. and a hydrogen pressure of from 101to 20786 kPa to produce a selectivated dewaxing catalyst;

(d) contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions; and.

(e) hydrofinishing the dewaxed product from step (d) with a mesoporoushydrofinishing catalyst from the M41S family under effectivehydrofinishing conditions.

A further embodiment relates to a process for preparing a lubricatingoil basestock having a VI of at least about 125 which comprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) adding at least one oxygenate to the liquid product from step (b) toprovide a second liquid product containing at least about 100 wppmoxygen,

(d) contacting the second liquid product from step (c) with a dewaxingcatalyst at a temperature of from 120 to 400° C. and a hydrogen pressureof from 791 to 20786 kPa for a time effective to selectivate thedewaxing catalyst; and

(e) contacting the selectivated dewaxing catalyst from step (d) with atleast one of the second liquid product from step (c) or the liquidproduct from step (b) under catalytically effective dewaxing conditions.

Another embodiment relates to a process for preparing a lubricating oilbasestock having a VI of at least about 125 which comprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) adding at least one alcohol, carboxylic acid, ester, aldehyde,ketone or ether to the liquid product from step (b) to provide a secondliquid product containing at least about 100 wppm oxygen;

(d) contacting the second liquid product from step (c) with a dewaxingcatalyst which contains at least one molecular sieve containing at leastone 10 or 12 ring channel at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst; and

(e) contacting the selectivated dewaxing catalyst from step (d) with atleast one of the second liquid product from step (c) or the liquidproduct from step (b) under catalytically effective dewaxing conditions.

Yet another embodiment relates to a process for preparing a lubricatingoil basestock having a VI of at least about 125 which comprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) adding at least one alcohol, carboxylic acid, ester, aldehyde,ketone or ether to the liquid product from step (b) to provide a secondliquid product containing at least about 100 wppm oxygen;

(d) contacting the second liquid product from step (c) with a dewaxingcatalyst which contains at least one molecular sieve containing at leastone 10 or 12 ring channel at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst;

(e) contacting the selectivated dewaxing catalyst from step (d) with atleast one of the second liquid product from step (c) or the liquidproduct from step (b) under catalytically effective dewaxing conditions;and

(f) hydrofinishing the dewaxed product from step (e) with ahydrofinishing catalyst under effective hydrofinishing conditions.

A still further embodiment relates to a process for preparing alubricating oil basestock having a VI of at least about 125 whichcomprises:

(a) hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions;

(b) stripping the hydrotreated feedstock to separate gaseous from liquidproduct;

(c) adding at least one alcohol, carboxylic acid, ester, aldehyde,ketone or ether to the liquid product from step (b) to provide a secondliquid product containing at least about 100 wppm oxygen;

(d) contacting the second liquid product from step (c) with a dewaxingcatalyst which contains ZSM-48 and a metal hydrogenation component whichcontains at least one of Pt or Pd at a temperature of from 120 to 400°C. and a hydrogen pressure of from 791 to 20786 kPa for a time effectiveto selectivate the dewaxing catalyst;

(e) contacting the selectivated dewaxing catalyst from step (d) with atleast one of the second liquid product from step (c) or the liquidproduct from step (b) under catalytically effective dewaxing conditions;and

(f) hydrofinishing the dewaxed product from step (e) with ahydrofinishing catalyst from the M41S family under effectivehydrofinishing conditions.

The basestocks according to the invention meet the requirements of aGroup III basestock and can be prepared in high yields while at the sametime possessing excellent properties such as high VI and low pour point.Selective oxygenate activation of the dewaxing catalyst further improvesboth yield and VI.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic flow diagram of the process.

FIG. 2 is a graph showing the effect of temperature on selectivity for aselectivated catalyst.

DETAILED DESCRIPTION OF THE INVENTION

Feedstocks

The feedstock used in the process of the invention are wax-containingfeeds that boil in the lubricating oil range, typically having a 10%distillation point greater than 650° F. (343° C.), measured by ASTM D 86or ASTM 2887, and are derived from mineral or synthetic sources. The waxcontent of the feedstock is at least about 50 wt. %, based on feedstockand can range up to 100 wt. % wax. The wax content of a feed may bedetermined by nuclear magnetic resonance spectroscopy (ASTM D5292), bycorrelative ndM methods (ASTM D3238) or by solvent methods (ASTM D3235).The waxy feeds may be derived from a number of sources such as oilsderived from solvent refining processes such as raffinates, partiallysolvent dewaxed oils, deasphalted oils, distillates, vacuum gas oils,coker gas oils, slack waxes, foots oils and the like, andFischer-Tropsch waxes. Preferred feeds are slack waxes andFischer-Tropsch waxes. Slack waxes are typically derived fromhydrocarbon feeds by solvent or propane dewaxing. Slack waxes containsome residual oil and are typically deoiled. Foots oils are derived fromdeoiled slack waxes. Fischer-Tropsch waxes are prepared by theFischer-Tropsch synthetic process.

Feedstocks may have high contents of nitrogen- and sulfur-contaminants.Feeds containing up to 0.2 wt. % of nitrogen, based on feed and up to3.0 wt. % of sulfur can be processed in the present process. Feedshaving a high wax content typically have high viscosity indexes of up to200 or more. Sulfur and nitrogen contents may be measured by standardASTM methods D5453 and D4629, respectively.

For feeds derived from solvent extraction, the high boiling petroleumfractions from atmospheric distillation are sent to a vacuumdistillation unit, and the distillation fractions from this unit aresolvent extracted. The residue from vacuum distillation may bedeasphalted. The solvent extraction process selectively dissolves thearomatic components in an extract phase while leaving the moreparaffinic components in a raffinate phase. Naphthenes are distributedbetween the extract and raffinate phases. Typical solvents for solventextraction include phenol, furfural and N-methyl pyrrolidone. Bycontrolling the solvent to oil ratio, extraction temperature and methodof contacting distillate to be extracted with solvent, one can controlthe degree of separation between the extract and raffinate phases.

Hydrotreating

For hydrotreating, the catalysts are those effective for hydrotreatingsuch as catalysts containing Group 6 metals (based on the IUPAC PeriodicTable format having Groups from 1 to 18), Groups 8–10 metals, andmixtures thereof. Preferred metals include nickel, tungsten, molybdenum,cobalt and mixtures thereof. These metals or mixtures of metals aretypically present as oxides or sulfides on refractory metal oxidesupports. The mixture of metals may also be present as bulk metalcatalysts wherein the amount of metal is 30 wt. % or greater, based oncatalyst. Suitable metal oxide supports include oxides such as silica,alumina, silica-aluminas or titania, preferably alumina. Preferredaluminas are porous aluminas such as gamma or eta. The amount of metals,either individually or in mixtures, ranges from about 0.5 to 35 wt. %,based on the catalyst. In the case of preferred mixtures of groups 9–10metals with group 6 metals, the groups 9–10 metals are present inamounts of from 0.5 to 5 wt. %, based on catalyst and the group 6 metalsare present in amounts of from 5 to 30 wt. %. The amounts of metals maybe measured by atomic absorption spectroscopy, inductively coupledplasma-atomic emission spectrometry or other methods specified by ASTMfor individual metals.

The acidity of metal oxide supports can be controlled by addingpromoters and/or dopants, or by controlling the nature of the metaloxide support, e.g., by controlling the amount of silica incorporatedinto a silica-alumina support Examples of promoters and/or dopantsinclude halogen, especially fluorine, phosphorus, boron, yttria,rare-earth oxides and magnesia. Promoters such as halogens generallyincrease the acidity of metal oxide supports while mildly basic dopantssuch as yttria or magnesia tend to decrease the acidity of suchsupports.

Hydrotreating conditions include temperatures of from 150 to 400° C.,preferably 200 to 350° C., a hydrogen partial pressure of from 1480 to20786 kPa (200 to 3000 psig), preferably 2859 to 13891 kPa (400 to 2000psig), a space velocity of from 0.1 to 10 LHSV, preferably 0.1 to 5LHSV, and a hydrogen to feed ratio of from 89 to 1780 m³/m³ (500 to10000 scf/B), preferably 178 to 890 m³/m³.

Hydrotreating reduces the amount of nitrogen- and sulfur-containingcontaminants to levels which will not unacceptably affect the dewaxingcatalyst in the subsequent dewaxing step. Also, there may be certainpolynuclear aromatic species which will pass through the present mildhydrotreating step. These contaminants, if present, will be removed in asubsequent hydrofinishing step.

During hydrotreating, less than 5 wt. % of the feedstock, preferablyless than 3 wt. %, more preferably less than 2 wt. %, is converted to650° F. (343° C.) minus products to produce a hydrotreated feedstockwhose VI increase is less than 4, preferably less than 3, morepreferably less than 2 greater than the VI of the feedstock. The highwax contents of the present feeds results in minimal VI increase duringthe hydrotreating step.

The hydrotreated feedstock may be passed directly to the dewaxing stepor preferably, stripped to remove gaseous contaminants such as hydrogensulfide and ammonia prior to dewaxing. Stripping can be by conventionalmeans such as flash drums or fractionators.

Dewaxing Catalyst and Oxygenate Treatment

The present process for the catalytic dewaxing of waxy feeds utilizes acatalyst that has been activated by contacting the catalyst with anoxygenate. A preferred dewaxing catalyst is one whose mode of dewaxingis by isomerizing wax molecules to isomerates with boiling points in thelube range.

The dewaxing catalyst may be either crystalline or amorphous.Crystalline materials are molecular sieves that contain at least one 10or 12 ring channel and may be based on aluminosilicates (zeolites), ormay be based on aluminophosphates. Zeolites used for oxygenate treatmentmay contain at least one 10 or 12 channel. Examples of such zeolitesinclude ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57,ferrierite, EU-1, NU-87, ITQ-13 and MCM-71. Examples ofaluminophosphates containing at least one 10 ring channel includeSAPO-11 and SAPO-41. Examples of molecular sieves containing 12 ringchannels include zeolite beta, ZSM-12, MCM-68 SAPO-5, SAPO-31, MAPO-36,ZSM-18, mordenite, faujasite and offretite. It should be noted that adewaxing catalyst such as ZSM-5 can have altered dewaxing properties byadjusting catalyst properties, such as acidity, metal dispersion andcatalyst particle size as noted in U.S. Pat. No. 6,294,077. Themolecular sieves are described in U.S. Pat. Nos. 5,246,566, 5,282,958,4,975,177, 4,397,827, 4,585,747, 5,075,269 and 4,440,871. MCM-68 isdescribed in U.S. Pat. No. 6,310,265. MCM-71 and ITQ-13 are described inPCT published applications WO 0242207 and WO 0078677. Preferredcatalysts include ZSM-48, ZSM-22 and ZSM-23. Especially preferred isZSM-48. As used herein, ZSM-48 includes EU-2, EU-11 and ZBM-30 which arestructurally equivalent to ZSM-48. The molecular sieves are preferablyin the hydrogen form. Reduction can occur in situ during the dewaxingstep itself or can occur ex situ in another vessel.

Amorphous dewaxing catalysts include alumina, fluorided alumina,silica-alumina, fluorided silica-alumina and silica-alumina doped withGroup 3 metals. Such catalysts are described for example in U.S. Pat.Nos. 4,900,707 and 6,383,366.

The dewaxing catalysts are bifunctional, i.e., they are loaded with ametal hydrogenation component, which is at least one Group 6 metal, atleast one Group 8–10 metal, or mixtures thereof. Preferred metals areGroups 9–10 metals. Especially preferred are Groups 9–10 noble metalssuch as Pt, Pd or mixtures thereof (based on the IUPAC Periodic Tableformat having Groups from 1 to 18). These metals are loaded at the rateof 0.1 to 30 wt. %, based on catalyst. Catalyst preparation and metalloading methods are described for example in U.S. Pat. No. 6,294,077,and include for example ion exchange and impregnation using decomposablemetal salts. Metal dispersion techniques and catalyst particle sizecontrol are described in U.S. Pat. No. 5,282,958. Catalysts with smallparticle size and well dispersed metal are preferred.

The molecular sieves are typically composited with binder materials thatare resistant to high temperatures and may be employed under dewaxingconditions to form a finished dewaxing catalyst or may be binderless(self-bound). The binder materials are usually inorganic oxides such assilica, alumina, silica-aluminas, binary combinations of silicas withother metal oxides such as titania, magnesia, thoria, zirconia and thelike and tertiary combinations of these oxides such assilica-alumina-thoria and silica-alumina magnesia. The amount ofmolecular sieve in the finished dewaxing catalyst is from 10 to 100,preferably 35 to 100 wt. %, based on catalyst. Such catalysts are formedby methods such spray drying, extrusion and the like. The dewaxingcatalyst may be used in the sulfided or unsulfided form, and ispreferably in the sulfided form.

Dewaxing conditions include temperatures of from 250–400° C., preferably275 to 350° C., pressures of from 791 to 20786 kPa (100 to 3000 psig),preferably 1480 to 17339 kPa (200 to 2500 psig), liquid hourly spacevelocities of from 0.1 to 10 hr⁻¹, preferably 0.1 to 5 hr⁻¹ and hydrogentreat gas rates from 45 to 1780 m³/m³ (250 to 10000 scf/B), preferably89 to 890 m³/m³ (500 to 5000 scf/B).

Oxygenates used to selectively activate the dewaxing catalyst areorganic, oxygen-containing compounds (organo-oxygenates) which formwater under hydrodewaxing conditions. Oxygenates include carboxylicacids, alcohols including polyols, esters, aldehydes, ethers, ketonesand mixtures thereof, or an inorganic oxygenate which is water.Preferred oxygenates are alcohols, esters, ethers and carboxylic acids,especially alcohols. The organo moieties contain at least 1 carbon atomand may range up to oxygen contained in oxidized hydrocarbon feeds inthe lube boiling range (343° C.+as measured by ASTM D 86 or ASTM 2887).

The feed used to selectively activate the catalyst contains at leastabout 100 wppm, measured as oxygen, of at least one oxygenate,preferably at least about 400 wppm, measured as oxygen, of at least oneoxygenate. Amounts of oxygenates greater than 10000 wppm may be used ifdesired as such amounts will not adversely affect the dewaxing processor products. The total oxygen content of an oxygenate can be measured byinstrumental methods such as neutron activation analysis which may becombined with high resolution proton nuclear magnetic resonance, gaschromatography with oxygen flame ionization detector, gaschromatography-mass spectrometry (GC-MS) or fourier transform infraredspectroscopy. Neutron activation analysis is preferred for lowconcentrations of oxygenates. Oxygenate contents of feeds (as oxygenate)may be determined by proton nuclear magnetic resonance or by GC-MS.

Various methods have been proposed for measuring the selectivity ofdewaxing catalysts. In one method described in J. Catalysis, 1984, 86,24–31, a feedstock is catalytically dewaxed over the zeolite whoseselectivity is determined at various reaction severities to achievedifferent product pour points. The conversion required to achieve agiven degree of dewaxing may then be compared with a reference catalystsuch as ZSM-5 to determine relative selectivity. In U.S. Pat. No.5,282,958, selectivity is measured for a given molecular sieve having adefined crystallite size and pore diameter by measuring theisomerization of n-hexadecane under a given set of test conditions.

In the present invention, selectivity for a given catalyst is defined asthe fractional amount of lube boiling range isomerate formed at thetarget pour point from the wax component of the feed. The improvement inselectivity as a result of oxygenate treatment for a given dewaxingcatalyst is to isomerize at least 4 relative % more of the wax componentinto lube boiling range isomerate at the pour point target, preferablyat least 6 relative %, more preferably at least 10 relative %.

The selectivity improvement for any give dewaxing catalyst may becalculated as illustrated in the hypothetical example given in thefollowing chart showing isomerate yield improvement at equivalent pourpoint for dewaxing a waxy feed. Catalyst A and Catalyst B (which isCatalyst A treated with oxygenate). The yield for the example isobtained by adjusting if necessary dewaxing conditions of temperatureand space velocity to achieve equivalent pour point.

Catalyst A Catalyst B (untreated) (oxygenate treated) Wax content offeed 90.0% 90.0% Yield of isomerate 61.0 wt. % 72.0 wt. % at target pourIsomerate selectivity 0.567* 0.689* Selectivity improvement 1.215**Relative selectivity 21.5%*** improvement % *Calculation: [61.0 − (100 −90)]/90 = 0.567 [72.0 − (100 − 90)]/90 = 0.689 **0.689/0.567 = 1.215; noimprovement is 0.567/0.567 = 1.0 ***(1.215 − 1.000) × 100 = 21.5%

For any given catalyst, isomerate yield should improve with increasingwax content of the feed. Thus feeds with higher wax contents, e.g.,greater than 40 wt. %, based on feed, are preferred.

Hydrofinishing

At least a portion of the product from dewaxing is passed directly to ahydrofinishing step without disengagement. It is preferred tohydrofinish the product resulting from dewaxing in order to adjustproduct qualities to desired specifications. Hydrofinishing is a form ofmild hydrotreating directed to saturating any lube range olefins andresidual aromatics as well as to removing any remaining heteroatoms andcolor bodies. The post dewaxing hydrofinishing is usually carried out incascade with the dewaxing step. Generally the hydrofinishing will becarried out at temperatures from about 150° C. to 350° C., preferably180° C. to 250° C. Total pressures are typically from 2859 to 20786 kPa(about 400 to 3000 psig). Liquid hourly space velocity is typically from0.1 to 5 LHSV (hr⁻¹), preferably 0.5 to 3 hr⁻¹ and hydrogen treat gasrates of from 44.5 to 1780 m³/m³ (250 to 10,000 scf/B).

Hydrofinishing catalysts are those containing Group 6 metals (based onthe IUPAC Periodic Table format having Groups from 1 to 18), Groups 8–10metals, and mixtures thereof. Preferred metals include at least onenoble metal having a strong hydrogenation function, especially platinum,palladium and mixtures thereof. The mixture of metals may also bepresent as bulk metal catalysts wherein the amount of metal is 30 wt. %or greater based on catalyst. Suitable metal oxide supports include lowacidic oxides such as silica, alumina, silica-aluminas or titania,preferably alumina. The preferred hydrofinishing catalysts for aromaticssaturation will comprise at least one metal having relatively stronghydrogenation function on a porous support. Typical support materialsinclude amorphous or crystalline oxide materials such as alumina,silica, and silica-alumina. The metal content of the catalyst is oftenas high as about 20 weight percent for non-noble metals. Noble metalsare usually present in amounts no greater than about 1 wt. %. Apreferred hydrofinishing catalyst is a mesoporous material belonging tothe M41S class or family of catalysts. The M41S family of catalysts aremesoporous materials having high silica contents whose preparation isfurther described in J. Amer. Chem. Soc., 1992, 114, 10834. Examplesincluded MCM-41, MCM-48 and MCM-50. Mesoporous refers to catalystshaving pore sizes from 15 to 100 Å. A preferred member of this class isMCM-41 whose preparation is described in U.S. Pat. No. 5,098,684. MCM-41is an inorganic, porous, non-layered phase having a hexagonalarrangement of uniformly-sized pores. The physical structure of MCM-41is like a bundle of straws wherein the opening of the straws (the celldiameter of the pores) ranges from 15 to 100 Angstroms. MCM-48 has acubic symmetry and is described for example is U.S. Pat. No. 5,198,203whereas MCM-50 has a lamellar structure. MCM-41 can be made withdifferent size pore openings in the mesoporous range. The mesoporousmaterials may bear a metal hydrogenation component, which is at leastone of Group 8, Group 9 or Group 10 metals. Preferred are noble metals,especially Group 10 noble metals, most preferably Pt, Pd or mixturesthereof.

Generally the hydrofinishing will be carried out at temperatures fromabout 150° C. to 350° C., preferably 180° C. to 250° C. Total pressuresare typically from 2859 to 20786 kPa (about 400 to 3000 psig). Liquidhourly space velocity is typically from 0.1 to 5 LHSV (hr⁻¹), preferably0.5 to 3 hr⁻¹ and hydrogen treat gas rates of from 44.5 to 1780 m³/m³(250 to 10,000 scf/B).

Catalyst Preparation and Process Description

Since normal hydrocarbon feedstocks derived from petroleum containamounts of sulfur and nitrogen that are detrimental to dewaxingcatalysts, it is preferred that such feedstocks are hydrotreated priorto dewaxing. Thus the feedstocks to the present catalytic dewaxingprocess that contain unacceptable levels of sulfur and nitrogencontaminants are preferably hydroprocessed and subsequently stripped toremove gaseous sulfur- and nitrogen-containing contaminants such ashydrogen sulfide and ammonia. The hydrotreated feedstocks are then sentto the dewaxing step.

The catalysts used in the catalytic dewaxing step are usually purchasedfrom a catalyst manufacturer. The user has the option of metal-loadingthe catalyst or purchasing the catalyst in the metal-loaded form. Asnoted previously, metal loading can be accomplished by impregnating thedewaxing catalyst with a decomposable metal salt such as an amine salt,e.g., platinum tetramine complex followed by heating. Sulfiding can beaccomplished by treating the metal loaded catalyst with a sulfidingmixture such as hydrogen/hydrogen sulfide or other sulfiding agent, orby contacting the catalyst with hydrogen and a feedstock spiked with asulfiding agent or by using a feedstock containing organo sulfurcompounds.

In order to selectively activate (selectivate) the dewaxing catalyst,the oxygenate or mixture of oxygenates may be added directly to thehydrocarbon feed to be dewaxed. Alternatively, the dewaxing catalyst canbe selectively activated separately and the activated catalyst used inthe dewaxing process. In the former process, a hydrocarbon feedcontaining at least about 100 wppm, measured as oxygen, of at least oneoxygenate is contacted with the dewaxing catalyst under dewaxingconditions. The time effective to selectivate that catalyst is at leastone hour, preferably at least 24 hours. The catalyst selectivation mayalso be followed by monitoring the yield of isomerate from dewaxing.Alternatively, the dewaxing catalyst can be selectively activated priorto use in the dewaxing process. In this case, the dewaxing catalyst isheated at a temperature of from 120 to 400° C. and a hydrogen pressureof from 101 to 20786 kPa (0 to 3000 psig) in the presence of a feedcontaining at least about 100 wppm, measured as oxygen, of at least oneoxygenate. The time effective to selectivate the catalyst is at leastone hour, preferably at least 24 hours. The catalyst selectivation mayalso be monitored by testing catalyst samples for increased isomerateyield in the dewaxing process. The feed may be the same or differentfrom the hydrocarbon feed to be dewaxed. Thus the feed may either be acarrier feed or the hydrocarbon feed to be dewaxed. If the feed is acarrier feed, it is preferred that the carrier be a hydrocarbon such asproduct resulting from the present catalytic dewaxing process. As notedpreviously, the dewaxing catalyst may be used in the sulfided orunsulfided form and may be reduced.

Catalyst preparation and subsequent dewaxing can be accomplished in asingle reactor or in separate reactors. In a preferred embodiment, anoble metal loaded ZSM-48 dewaxing catalyst is placed in a reactor andhydrogen and a carrier feedstock containing sulfiding agent added to thereactor. It is preferred that the carrier feedstock be similar to abasestock cut expected as a final product, e.g., a 100N oil. Thecatalyst is reduced, sulfided or both reduced and sulfided. The reducedand/or sulfided catalyst can then be selectively activated by contactingwith a carrier containing at least one oxygenate. The carrier can beeither the feedstock to be dewaxed or some other hydrocarbon feedstocksuch as the carrier used to sulfide the catalyst.

Once the catalyst has been selectively activated with oxygenate(s), thefeedstock to be dewaxed is added to the reactor and dewaxing takes placeunder conditions defined above. Further oxygenate treatment may be addedas needed to maintain catalyst activity.

The product from catalytic dewaxing may be sent to hydrofinishing in aseparate reactor without any intervening disengagement. Direct cascadefrom dewaxer to hydrofinisher is preferred thus avoiding the expenseinvolved in an additional stripping step. Hydrofinishing is done in thepresence of hydrogen and a hydrofinishing catalyst. The hydrofinishingreaction conditions are noted hereinbefore. Hydrofinishing is useful toremove color bodies, enhance stability and improve toxicologicalproperties.

The hydrofinished product is then fractionated to isolate desiredlubricant products. The individual cuts of lubricants products areattractive as basestocks for meeting Group II and Group IIIrequirements. These Group classifications are those used by the AmericanPetroleum Institute (API). API Group II basestocks have a saturatescontent of 90 wt. % or greater, a sulfur content of not more than 0.03wt. % and a VI greater than 80 but less than 120. API Group IIIbasestocks have the same requirements as Group II basestocks except thatthe VI is greater than 120.

The base stocks produced the present process have a unique combinationof properties. The basestocks have VI from 145 to 155, a viscosity at100° C. of from 3.0 to 4.3 cSt, preferably 3.0 to 3.6 and a pour pointof from −15 to −40° C. The combination of very high VI at very lowviscosity and pour point in indicative of the outstanding qualities ofthe base stocks.

Referring now to FIG. 1, a waxy feedstock such as a slack wax is fedthrough line 10 to hydrotreating unit 14. Hydrogen is added tohydrotreating unit 14 through line 12. Hydrotreater 14 is loaded with abed of hydrotreating catalyst 16. Hydrotreated feedstock is conductedthrough line 18 to stripper 20 and light gases are removed through line22. Liquid product is then sent from striper 20 through line 24 tohydrodewaxing unit 28. Additional hydrogen is added through line 26.Hydrodewaxing unit 28 is loaded with a bed of hydrodewaxing catalyst 30which catalyst has been selectively activated by oxygenate treatment.Hydrodewaxed product is then sent through line 32 to hydrofinishing unit34 which is loaded with a bed of hydrofinishing catalyst 36.Hydrofinished product is then sent through line 38 to vacuum stripper40. Light products are removed through line 42 and remaining liquidproduct sent through line 44 to a vacuum distillation unit (not shown).

The invention is further illustrated by the following examples that arenot intended as limiting.

EXAMPLES Example 1

This example illustrates that processing clean feeds with a reducedsulfided and oxygenate treated hydrodewaxing catalyst can produce a highquality dewaxed oil at excellent yield. The feed is a 600N slack wax(SW) hydrotreated at 340° C. whose properties are given in Table 1.Viscosity was measured using standard ASTM tests (D445-94 and D2270-91)using a Houillon Automated Viscometer with a repeatability of 0.5%. Pourpoints are determined by standard ASTM test (D 97). Sulfur and nitrogencontents may be measured by standard ASTM methods D5453 and D4629,respectively. The error limits for yield and pour points are ±1 and ±3,respectively.

TABLE 1 Viscosity, cSt at 100° C. 8.03 Nitrogen, Wppm 43 Sulfur, Wppm1230 Oil in wax, wt % 23.8

The feed from Table 1 was hydrotreated with Akzo Nobel KF848 catalystunder the following hydrotreating conditions: 340° C., LHSV of 0.7v/v/h, psig (6996 kPa), treat rate of 1500 scf/B H₂ (267 m³/m³). Thehydrotreated product's 370° C.+yield was 94.1 wt. % on feed. Thehydrotreated product's properties are given in Table 2.

TABLE 2 Viscosity, cSt at 100° C. 6.702 Nitrogen, Wppm 0.48 Sulfur, Wppm1.5

The hydrotreated product was hydrodewaxed (HDW) in a reactor with acatalyst comprising ZSM-48 catalyst bound with 35 wt % gamma alumina andloaded with 0.6 wt. % Pt. The catalyst was then dried at 120° C.,reduced in hydrogen, and sulfided at temperatures up to 320° C. with 400wppm hydrogen sulfide in nitrogen to breakthrough. This catalyst wasthen subjected to an in-situ oxygenate selectivation procedure using aFischer Tropsch wax containing 600 wppm oxygenates as measured byneutron activation. The selectivation and hydrodewaxing conditions wereas follows: 1 v/v/h, 1000 psig (6996 kPa), 2500 scf/B H₂ (445 m³/m³).The hydrodewaxed results are given in Table 3.

TABLE 3 Average Reactor Temp. ° C. 320 325 330 370° C.+ Yield, wt. % onfeed to HDW 83.8 78.6 69.6 Product Properties Viscosity at 100° C. (cSt)6.883 6.661 6.514 VI 154 150 144 Pour Point (° C.) −7 −17 −33

Example 2

This example illustrates that processing clean feeds with a reducedsulfided and oxygenate treated hydrodewaxing catalyst can produce a highquality dewaxed oil at excellent yield The feed is a 150 N slack waxwhose properties are given in Table 4. The feed was hydrotreated at 345°C.

TABLE 4 Viscosity, cSt at 100° C. 3.6 Nitrogen, Wppm 0.4 Sulfur, Wppm120 Oil in wax, wt. % 7.0

The feed from Table 4 was hydrotreated with Akzo Nobel KF848 catalystunder the following hydrotreating conditions: 345° C., 0.7 v/v/h, 1000psig (6996 kPa), 1500 scf/B H₂ (267 m³/m³). The hydrotreated product's370° C.+yield was 93.2 wt. % on feed. The hydrotreated product'sproperties are given in Table 5.

TABLE 5 Viscosity, cSt at 100° C. 3.4 Nitrogen, Wppm 0.1 Sulfur, Wppm 0

The hydrotreated product was hydrodewaxed with a catalyst comprisingZSM-48 catalyst bound with 35 wt % gamma alumina and loaded with 0.6 wt.% Pt. The catalyst was then dried at 120° C., reduced in hydrogen, andsulfided at temperatures up to 320° C. with 400 wppm hydrogen sulfide innitrogen to breakthrough. This catalyst was then subjected to an in-situselectivation procedure using a Fischer Tropsch wax containing 600 wppmoxygenates as measured by neutron activation. The selectivation andhydrodewaxing conditions were as follows: 1 v/v/h, psig (6996 kPa), 2500scf/B H₂ (445 m³/m³). The hydrodewaxed results are given in Table 6.

TABLE 6 Average Reactor Temp. ° C. 330 335 370° C.+ Yield, wt. % on feedto HDW 81.8 67.2 370° C.+ Product Properties Viscosity at 100° C. (cSt)3.495 3.428 VI 158 148 Pour Point (° C.) −5 −29

The product produced at a reactor temperature of 335° C. is unique inthat its combination of VI, viscosity and pour point demonstrate a veryhigh quality product. As shown by the data, the base stock has a veryhigh VI (148), a very low viscosity (3.428) at a low pour point (−29). Aproduct having such a high VI at the very low viscosity and pour pointis indicative of the unusual combination of properties of this basestock.

Example 3

This example compares the performance of a reduced and sulfided catalystwith that of a reduced, sulfided catalyst that has been additionallyoxygenate selectivated in-situ with a Fischer Tropsch feedstreamcontaining 600 ppm of oxygenates. The feed is a 150N slack wax (SW)which has been hydrotreated with Akzo Nobel KF848 catalyst under thefollowing hydrotreating conditions: 345° C., 0.7 v/v/h, psig (6996 kPa),1500 scf/B H₂ (267 m³/m³). The hydrotreated product's 370° C.+yield was93.2 wt. % on feed. The hydrotreated product's properties are given inTable 7.

TABLE 7 Feed: 150N SW (7.0% Oil In Wax (OIW)) B C A Reduced + Reduced +Reduced + Sulfided + Sulfided + Sulfided oxygenate oxygenate CatalystTreatment only Condition A Condition B Average Reactor 329 340 345Temperature, ° C. 370° C.+ Lube Properties 370° C.+ Lube yield, wt. %52.6 68.4 53.0 on feed to Hydrodewaxer Viscosity, cSt at 100° C. 3.33.404 3.373 VI 134 148 139 370° C.+ Pour Point ° C. −26 −27 −37

Table 5 shows that the catalyst selectivated by reduction, sulfiding andoxygenate treatment with has superior low temperature properties and VIat constant yield over the catalyst treated only by reduction andsulfiding (column A vs. column C). Alternatively at constant pour point(column A vs. column B) the catalyst selectivated with oxygenates givesa yield credit of 15.8 wt. % on feed. Moreover, the product shown incolumn B is unique in that its combination of VI, viscosity and pourpoint demonstrate a very high quality product. As shown by the data, thebase stock has a very high VI (148), a very low viscosity (3.404) at alow pour point (−27).

Wax isomerate selectivity is defined as:

${Selectivity} = \frac{{370{^\circ}\mspace{14mu}{C.\;{+ \;{yield}}}\mspace{11mu}(\%)} - {{Feed}\mspace{14mu}{oil}\mspace{14mu}{content}\mspace{11mu}(\%)}}{{Feed}\mspace{14mu}{Wax}\mspace{14mu}{content}\mspace{11mu}(\%)}$

Selectivity Improvement is defined as:

${{Selectivity}\mspace{14mu}{Improvement}} = \frac{{Selectivated}\mspace{14mu}{Catalyst}\mspace{14mu}{Selectivity}}{{Base}\mspace{14mu}{Catalyst}\mspace{14mu}{Selectivity}}$

Calculation example for Example 3:

${{Selectivity}\mspace{14mu}{Improvement}} = {\frac{\left( {68.4 - 7.0} \right)/93.0}{\left( {52.6 - 7.0} \right)/93.0} = {\frac{0.66}{0.49} = {1.34\mspace{14mu}{or}\mspace{14mu} 34\%\mspace{14mu}{over}\mspace{14mu}{base}\mspace{14mu}{case}}}}$

Example 4

This example presents a comparison of reduced, sulfided catalyst withreduced, sulfided plus oxygenate treatment catalyst for a 600N SW (16.5%OIW) feedstock. The feed properties are listed in table 8

TABLE 8 Viscosity, cSt at 100° C. 7.95 Nitrogen, Wppm 14 Sulfur, Wppm912 Oil in wax, Wt. % 16.5

This example compares the performance of a reduced and sulfided catalystwith that of a reduced, sulfided catalyst that has been additionallyselectivated with a Fischer Tropsch feedstream containing 600 ppm ofoxygenates. The feed is a 600N slack wax (SW) which has beenhydrotreated with Akzo Nobel KF848 catalyst under the followinghydrotreating conditions: 345° C., 0.7 v/v/h, 1000 psig (6996 kPa), 1500scf/B H₂ (267 m³/m³). The hydrotreated product's 370° C.+yield was 93.2wt. % on feed. The hydrotreated product's properties are given in Table9.

TABLE 9 Viscosity, cSt at 100° C. 7.2 Nitrogen, Wppm 5 Sulfur, Wppm 1

TABLE 10 Feed: 600N SW(16.5% OIW) A B Reduced + Reduced + CatalystTreatment Sulfided Sulfided + oxygenate Average Reactor 329 335Temperature, ° C. 370° C.+ Lube Properties 60.4 76.8 Viscosity, cSt at100° C. 6.8 6.8 VI 142 151 370° C.+ Pour Point ° C. −22 −20

Table 10 shows that the catalyst selectivated by reduction, sulfidingand oxygenate at constant pour point in comparison to the catalystselectivated with oxygenates (column A vs. column B), gives a yieldcredit of 16.4 wt. % on feed and a VI credit of 9 points.

Example 5

This example demonstrates the impact of higher temperature operation onselectivity on a selectivated catalyst. This example also demonstratesthat selectivation is reversible after a higher temperature operation aswell as the possibility to re-selectivated in-situ.

The ex-situ sulfided catalyst (Cat-C) was loaded and dried according tothe procedure described in Example 1.

As shown in FIG. 2:

-   -   Stage 1, the catalyst was lined-out with an oxygenate free        hydrotreated 150N slack wax.    -   Stage 2, the catalyst was then treated with the oxidized        hydrotreated 150N slack wax feedstock described in example 1        containing between 1000 and 3000 ppm oxygen (as oxygenate).        After Stage 2, the unit was washed using a medicinal grade white        oil to remove all traces of polars and aromatics. The catalyst        temperature was then increased to 350° C. under white oil at        1000 psig pressure and maintained at 350° C. for 36 hours. After        the 36 hours hold, the temperature was reduced to the operating        temperature of 328° C., this operation was also conducted under        white oil.    -   Stage 3, after the higher temperature treatment, was run for 10        days using the same oxygenate free hydrotreated 150N slack wax        used in stage 1. At the end of stage 3, the catalyst was exposed        to the oxidized hydrotreated 150N slack wax feedstock described        in example 1 containing between 1000 and 3000 ppm oxygenate, at        328° C. for 3 days.    -   Stage 4, after the higher temperature treatment, was run for 10        days using the same oxygenate free hydrotreated 150N slack wax        used in stage 1.

TABLE 11 Stage 2 Stage 3 Stage 4 Stage 1 Stage 1 Stage 2 Stage 3 Ex-situafter [O] after High after [O] Treatment sulfided treat Temp. treat Dayson Oil 8 14 38 49 Temperature (° C.) 329 325 328 328 370+ ° C. Yield(wt. %) 61.9 73.0 67.7 72.7 Selectivity Improvement Base +19 +10 +19 (%)370+ ° C. Isomerate K. 12.785 13.798 13.695 12.814 Viscosity @ 40° C.(cSt) 370+ ° C. Isomerate K. 3.371 3.571 3.515 3.393 Viscosity @ 100° C.(cSt) 370+ ° C. Isomerate 143 147 141 145 Viscosity Index 370+ ° C.Isomerate −19 −19 −23 −19 Pour Point (° C.)

Data in Table 11 and FIG. 2 demonstrate:

-   -   a partial loss of the yield credit after higher temperature        treatment (Stage 3 versus Stage 2)    -   that ZSM-48 can be “re-selectivated” in-situ after processing an        oxygenated containing feedstock. (Stage 4 versus Stage 3)

1. A process for preparing a lubricating oil basestock having a VI of atleast about 125 which comprises: (a) hydrotreating a lubricating oilfeedstock having a wax content of at least about 50 wt. %, based onfeedstock, with a hydrotreating catalyst under effective hydrotreatingconditions; (b) stripping the hydrotreated feedstock to separate gaseousfrom liquid product; (c) contacting a dewaxing catalyst containing analumina or alumina-containing binder with a stream containing from about100 wppm to 10,000 wppm, measured as oxygen, of at least one oxygenateat a temperature of from 120 to 400° C. and a hydrogen pressure of from791 to 20786 kPa to produce a selectivated dewaxing catalyst; and (d)contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions.
 2. A process for preparinga lubricating oil basestock having a VI of at least about 125 whichcomprises: (a) hydrotreating a lubricating oil feedstock having a waxcontent of at least about 50 wt. %, based on feedstock, with ahydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) adding at least one oxygenate to the liquid product fromstep (b) to provide a second liquid product containing from about 100wppm oxygen to 10,000 wppm, (d) contacting the second liquid productfrom step (c) with a dewaxing catalyst containing an alumina oralumina-containing binder at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst; and (e) contacting the selectivateddewaxing catalyst from step (d) with at least one of the second liquidproduct from step (c) or the liquid product from step (b) undercatalytically effective dewaxing conditions.
 3. The process of claims 1or 2 wherein the hydrotreating catalyst contains at least one Group 6,Group 9 or Group 10 metal.
 4. The process of claims 1 or 2 wherein thehydrotreating conditions include a temperature of from 150–400° C., apressure of from 1480–20786 kPa, a liquid hourly space velocity from0.1–10 hr⁻¹ and a hydrogen treat rate of 89–1780 m³/m³.
 5. The processof claims 1 or 2 wherein the dewaxing catalyst contains at least onemolecular sieve containing least one 10 or 12 ring channel.
 6. Theprocess of claim 5 wherein the molecular sieve is at least one of ZSM-5,ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57, ferrierite, EU-1, NU-87,SAPO-11, SAPO-41, ITO-13, MCM-71, zeolite beta, ZSM-12, MCM-68, SAPO-5,SAPO-31, MAPO-36, ZSM-18, offretite, mordenite or faujasite.
 7. Theprocess of claim 6 wherein the molecular sieve is ZSM-48.
 8. The processof claims 1 or 2 wherein the oxygenate is at least one alcohol,carboxylic acid, ester, aldehyde, ketone or ether.
 9. The process ofclaim 1 wherein the oxygenate is water.
 10. The process of claims 1 or 2wherein the dewaxing catalyst contains a metal hydrogenation component.11. The process of claims 1 or 2 wherein the dewaxing catalyst issulfided, reduced, or sulfided and reduced.
 12. The process of claims 1or 2 wherein dewaxing conditions include a temperature of from 250–400°C., a pressure of from 791–20786 kPa, a liquid hourly space velocityfrom 0.1–10 hr⁻¹ and a hydrogen treat rate of 45–1780 m³/m³.
 13. Theprocess of claims 1 or 2 further comprising a hydrofinishing step. 14.The process of claim 2 wherein the time effective to selectivate thedewaxing catalyst is at least about 1 hour.
 15. The process of claim 10wherein the metal hydrogenation component is at least one of Pt or Pd.16. The process of claim 1 wherein the stream is at least one oflubricating oil feedstock or lubricating oil basestock.
 17. A processfor preparing a lubricating oil basestock having a VI of at least about125 which comprises: (a) hydrotreating a lubricating oil feedstockhaving a wax content of at least about 50 wt. %, based on feedstock, wita hydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) contacting a dewaxing catalyst containing an alumina oralumina-containing binder which contains at least one molecular sievecontaining at least one 10 or 12 ring channel with a stream containingfrom about 100 wppm to 10,000 wppm, measured as oxygen, of at least onealcohol, carboxylic acid, ester, aldehyde, ketone or ether at atemperature of from 120 to 400° C. and a hydrogen pressure of from 101to 20786 kPa to produce a selectivated dewaxing catalyst; and (d)contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions.
 18. A process for preparinga lubricating oil basestock having a VI of at least about 125 whichcomprises: (a) hydrotreating a lubricating oil feedstock having a waxcontent of at least about 50 wt. %, based on feedstock, with ahydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) adding at least one alcohol, carboxylic acid, ester,aldehyde, ketone or ether to the liquid product from step (b) to providea second liquid product containing from about 100 wppm oxygen to 10,000wppm; (d) contacting the second liquid product from step (c) with adewaxing catalyst containing an alumina or alumina-containing binderwhich contains at least one molecular sieve containing at least one 10or 12 ring channel at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst; and (e) contacting the selectivateddewaxing catalyst from step (c) with at least one of the second liquidproduct from step (c) or the liquid product from step (b) undercatalytically effective dewaxing conditions.
 19. The process of claims17 or 18 wherein the hydrotreating catalyst contains at least one Group6, Group 9 or Group 10 metal.
 20. The process of claims 17 or 18 whereinthe hydrotreating conditions include a temperature of from 150–400° C.,a pressure of from 1480–20786 kPa, a liquid hourly space velocity from0.1–10 hr⁻¹ and a hydrogen treat rate of 89–1780 m³/m³.
 21. The processof claim 17 or 18 wherein the dewaxing catalyst is at least one ofZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57, ferrierite, EU-1,NU-87, SAPO-11, SAPO-41, ITQ-13, MCM-71, zeolite beta, ZSM-12, MCM-68,SAPO-5, SAPO-31, MAPO-36, ZSM-18, offretite, mordenite or faujasite. 22.The process of claim 21 wherein the molecular sieve is ZSM-48.
 23. Theprocess of claim 17 or 18 wherein the dewaxing catalyst contains a metalhydrogenation component.
 24. The process of claims 17 or 18 wherein thedewaxing catalyst is sulfided, reduced, or sulfided and reduced.
 25. Theprocess of claims 17 or 18 wherein dewaxing conditions include atemperature of from 250–400° C., a pressure of from 791–20786 kPa, aliquid hourly space velocity from 0.1–10 hr⁻¹ and a hydrogen treat rateof 45–1780 m³/m³.
 26. The process of claims 17 or 18 further comprisinga hydrofinishing step.
 27. The process of claim 18 wherein the timeeffective to selectivate the dewaxing catalyst is at least about 1 hour.28. The process of claim 17 wherein the stream is at least one oflubricating oil feedstock or lubricating oil basestock.
 29. The processof claim 23 wherein the metal hydrogenation is at least one of Pt or Pd.30. A process for preparing a lubricating oil basestock having a VI ofat least about 125 which comprises: (a) hydrotreating a lubricating oilfeedstock having a wax content of at least about 50 wt. %, based onfeedstock, wit a hydrotreating catalyst under effective hydrotreatingconditions; (b) stripping the hydrotreated feedstock to separate gaseousfrom liquid product; (c) contacting a dewaxing catalyst containing analumina or alumina-containing binder which contains at least onemolecular sieve containing at least one 10 or 12 ring channel with astream containing from about 100 wppm to 10,000 wppm, measured asoxygen, of at least one alcohol, carboxylic acid, ester, aldehyde,ketone or ether at a temperature of from 120 to 400° C. and a hydrogenpressure of from 101 to 20786 a to produce a selectivated dewaxingcatalyst; (d) contacting the selectivated dewaxing catalyst from step(c) with the liquid product from step (b) and dewaxing the liquidproduct under catalytically effective dewaxing conditions; and (e)hydrofinishing the dewaxed product from step (d) with a hydrofinishingcatalyst under effective hydrofinishing conditions.
 31. A process forpreparing a lubricating oil basestock having a VI of at least about 125which comprises: (a) hydrotreating a lubricating oil feedstock having awax content of at least about 50 wt. %, based on feedstock, with ahydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) adding at least One alcohol, carboxylic acid, ester,aldehyde, ketone or ether to the liquid product from step (b) to providea second liquid product containing from about 100 wppm oxygen to 10,000wppm; (d) contacting the second liquid product from step (c) with adewaxing catalyst containing an alumina or alumina-containing binderwhich contains at least one molecular sieve containing at least one 10or 12 ring channel at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst; (e) contacting the selectivateddewaxing catalyst from step (d) with at least one of the second liquidproduct from step (c) or the liquid product from step (b) undercatalytically effective dewaxing conditions; and (f) hydrofinishing thedewaxed product from step (e) with a hydrofinishing catalyst undereffective hydrofinishing conditions.
 32. The process of claims 30 or 31wherein the hydrotreating catalyst contains at least one Group 6, Group9 or Group 10 metal.
 33. The process of claims 30 or 31 wherein thehydrotreating conditions include a temperature of from 150–400° C., apressure of from 1480–20786 kPa, a liquid hourly space velocity from0.1–10 hr⁻¹ and a hydrogen treat rate of 89–1780 m³/m³.
 34. The processof claims 30 or 31 wherein the molecular sieve is at least one of ZSM-5,ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57, ferrierite, EU-1, NU-87,SAPO-11, SAPO-41, ITQ-13, MCM-71, zeolite beta, ZSM-12, MCM-68, SAPO-5,SAPO-31, MAPO-36, ZSM-18, offretite, mordenite or faujasite.
 35. Theprocess of claim 34 wherein the molecular sieve is ZSM-48.
 36. Theprocess of claims 30 or 31 wherein the dewaxing catalyst contains ametal hydrogenation component.
 37. The process of claims 30 or 31wherein the dewaxing catalyst is sulfided, reduced, or sulfided andreduced.
 38. The process of claim 30 or 31 wherein dewaxing conditionsinclude a temperature of from 250–400° C., a pressure of from 791–20786kPa, a liquid hourly space velocity from 0.1–10 hr⁻¹ and a hydrogentreat rate of 45–1780 m3/m³.
 39. The process of claims 30 or 31 whereinthe hydrofinishing catalyst is at least one of M41S family of catalysts.40. The process of claims 30 or 31 wherein hydrofinishing conditionsinclude a temperature of from 150–350° C., a pressure of from 2889–20786kPa, a liquid hourly space velocity from 0.1–5 hr⁻¹ and a hydrogen treatrate of 45–1780 m³/m³.
 41. The process of claim 31 wherein the timeeffective to selectivate the dewaxing catalyst is at least about 1 hour.42. The process of claim 30 wherein the stream is at least one oflubricating oil feedstock or lubricating oil basestock.
 43. The processof claim 36 wherein the metal hydrogenation component is at least one ofPt or Pd.
 44. A process for preparing a lubricating oil basestock havinga VI of at least about 125 which comprises: (a) hydrotreating alubricating oil feedstock having a wax content of at least about 50 wt.%, based on feedstock, with a hydrotreating catalyst under effectivehydrotreating conditions; (b) stripping the hydrotreated feedstock toseparate gaseous from liquid product; (c) contacting a dewaxing catalystcontaining an alumina or alumina-containing binder which contains ZSM-48and a metal hydrogenation component which contains at least one of Pt orPd with a stream containing from about 100 wppm to 10,000 wppm, measuredas oxygen, of at least one alcohol, carboxylic acid, ester, aldehyde,ketone or ether at a temperature of from 120 to 400° C. and a hydrogenpressure of from 101 to 20786 kPa to produce a selectivated dewaxingcatalyst; (d) contacting the selectivated dewaxing catalyst from step(c) with the liquid product from step (b) and dewaxing the liquidproduct under catalytically effective dewaxing conditions; and (e)hydrofinishing the dewaxed product from step (d) with a mesoporoushydrofinishing catalyst from the M41 S family under effectivehydrofinishing conditions.
 45. A process for preparing a lubricating oilbasestock having a VI of at least about 125 which comprises: (a)hydrotreating a lubricating oil feedstock having a wax content of atleast about 50 wt. %, based on feedstock, with a hydrotreating catalystunder effective hydrotreating conditions; (b) stripping the hydrotreatedfeedstock to separate gaseous from liquid product; (c) adding at leastone alcohol, carboxylic acid, ester, aldehyde, ketone or ether to theliquid product from step (b) to provide a second liquid productcontaining from about 100 wppm oxygen to 10,000 wppm; (d) contacting thesecond liquid product from step (c) with a dewaxing catalyst containingan alumina or alumina-containing binder which contains ZSM-48 and ametal hydrogenation component which contains at least one of Pt or Pd ata temperature of from 120 to 400° C. and a hydrogen pressure of from 791to 20786 kPa for a time effective to selectivate the dewaxing catalyst;(e) contacting the selectivated dewaxing catalyst from step (d) with atleast one of the second liquid product from step (c) or the liquidproduct from step (b) under catalytically effective dewaxing conditions;and (f) hydrofinishing the dewaxed product from step (e) with ahydrofinishing catalyst from the M41S family under effectivehydrofluishing conditions.
 46. The process of claims 44 or 45 whereinthe hydrotreating catalyst contains at least one Group 6, Group 9 orGroup 10 metal.
 47. The process of claims 44 or 45 wherein thehydrotreating conditions include a temperature of from 150–400° C., apressure of from 1480–20786 kPa, a liquid hourly space velocity from0.1–10 hr⁻¹ and a hydrogen treat rate of 89–1780 m³/m³.
 48. The processof claims 44 or 45 wherein the dewaxing catalyst is sulfided, reduced,or sulfided and reduced.
 49. The process of claim 44 or 45 whereindewaxing conditions include a temperature of from 250–400° C., apressure of from 791–20786 kPa, a liquid hourly space velocity from0.1–10 hr⁻¹ and a hydrogen treat rate of 45–1780 m³/m³.
 50. The processof claims 44 or 45 wherein hydrofinishing conditions include atemperature of from 150–350° C., a pressure of from 2889–20786 kPa, aliquid hourly space velocity from 0.1–5 hr⁻¹ and a hydrogen treat rateof 45–1780 m³/m³.
 51. The process of claim 45 wherein the time effectiveto selectivate the dewaxing catalyst is at least about 1 hour.
 52. Theprocess of claim 44 wherein the stream is at least one of lubricatingoil feedstock or lubricating oil basestock.
 53. A process for preparinga lubricating oil basestock having a VI of at least about 125 whichcomprises: (a) hydrotreating a lubricating oil feedstock having a waxcontent of at least about 50 wt. %, based on feedstock, with ahydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) contacting a dewaxing catalyst containing an alumina oralumina-containing binder which contains at least one molecular sievecontaining at least one 10 or 12 ring channel with a stream containingfrom about 100 wppm to 10,000 wppm, measured as oxygen, of water at atemperature of from 120 to 400° C. and a hydrogen pressure of from 101to 20786 kPa to produce a selectivated dewaxing catalyst; and (d)contacting the selectivated dewaxing catalyst from step (c) with theliquid product from step (b) and dewaxing the liquid product undercatalytically effective dewaxing conditions.
 54. A process for preparinga lubricating oil basestock having a VI of at least about 125 whichcomprises; (a) hydrotreating a lubricating oil feedstock having a waxcontent of at least about 50 wt. %, based on feedstock, with ahydrotreating catalyst under effective hydrotreating conditions; (b)stripping the hydrotreated feedstock to separate gaseous from liquidproduct; (c) adding water to the liquid product from step (b) to providea second liquid product containing from about 100 wppm oxygen to 10,000wppm; (d) contacting the second liquid product from step (c) with adewaxing catalyst containing an alumina or alumina-containing binderwhich contains at least one molecular sieve containing at least one 10or 12 ring channel at a temperature of from 120 to 400° C. and ahydrogen pressure of from 791 to 20786 kPa for a time effective toselectivate the dewaxing catalyst; and (e) contacting the selectivateddewaxing catalyst from step (d) with at least one of the second liquidproduct from step (c) or the liquid product from step (b) undercatalytically effective dewaxing conditions.